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A

Group 'A'

Attempt any five questions.

7 questions·2 marks each
1short2 marks

Write two important features of hybrid orbitals.

chemical-bondinghybridization
2short2 marks

Define the terms: (i) Primary standard solution (ii) Acidimetry

volumetric-analysisdefinitions
3numeric2 marks

How many coulombs are required to produce 50gm50\,\text{gm} of Al when electrode reaction is Al++++3eAlAl^{+++}+3e^{-}\rightarrow Al (atomic mass of Al=27Al=27)?

Numeric answer (C)

electrolysisfaradays-laws
4numeric2 marks

For a reaction, 2N2O54NO2+O22N_2O_5 \rightarrow 4NO_2+O_2, the rate of disappearance of N2O5N_2O_5 is 4×106 mol L1S14\times10^{-6}\ \text{mol L}^{-1}\text{S}^{-1}, what will be the rate of formation of NO2NO_2?

Numeric answer (mol L⁻¹ s⁻¹)

chemical-kineticsrate-of-reaction
5short2 marks

Write the action of heat on blue vitriol.

inorganic-chemistrycopper-compounds
6short2 marks

Write an example of each of the following: (i) Aldol Condensation (ii) Rosenmund's reduction

organic-chemistrynamed-reactions
7short2 marks

Write down the structure of a primary amine and a secondary amine from C3H9NC_3H_9N and give their IUPAC name.

organic-chemistryaminesiupac-nomenclature
B

Group 'B'

Attempt any two questions.

3 questions·5 marks each
8long5 marks

Define the terms: (i) titration error (ii) unknown solution. What volume of 10M10\,M HCl and 3M3\,M HCl should be mixed to obtain one litre of 6M6\,M HCl solution? [1+1+3][1+1+3]

volumetric-analysisdilutiondefinitions
9long5 marks

State enthalpy of combustion. If heat of formation of CO2CO_2, H2OH_2O and C6H12O6C_6H_{12}O_6 are 395 KJ mol1-395\ \text{KJ mol}^{-1}, 269.4 KJ mol1-269.4\ \text{KJ mol}^{-1} and 1169 KJ mol11169\ \text{KJ mol}^{-1} respectively. Calculate the heat of combustion of glucose. [1+4][1+4]

thermochemistryenthalpy-of-combustion
10long5 marks

Give chemical reaction for the preparation of ethanoic acid from (i) 1,1,1-trichloro ethane (ii) Methyl magnesium iodide (iii) ethane nitrile. How is ethanoic acid converted into methanoic acid? [3+2][3+2]

organic-chemistrycarboxylic-acidsconversions
C

Group 'C'

Attempt any one question.

2 questions·10 marks each
11long10 marks

Write down a structural formula and its IUPAC name of C4H10OC_4H_{10}O. How would you apply Victor Meyer's method for the distinction of propan-1-ol from propan-2-ol? Write an example of the following reactions: (i) oxo-process (ii) Baeyer's test. Convert propan-2-ol into propan-1-ol. [2+4+2+2][2+4+2+2]

organic-chemistryalcoholsiupac-nomenclature
12long10 marks

Define: (i) rate law equation (ii) Half life period for a reaction. How is order of a reaction differed from molecularity of reaction? The following rate data were obtained for the reaction 2A+BC2A+B\rightarrow C:

Expt No.[A] mol L⁻¹[B] mol L⁻¹initial rate of formation of C (mol L⁻¹ S⁻¹)
10.10.16.0×1036.0\times10^{-3}
20.30.27.2×1027.2\times10^{-2}
30.30.42.88×1042.88\times10^{-4}
40.40.12.4×1022.4\times10^{-2}

Calculate the rate of formation of C when [A]=0.5 mol L1[A]=0.5\ \text{mol L}^{-1} and B=0.2 mol L1B=0.2\ \text{mol L}^{-1}. [2+4+4][2+4+4]

chemical-kineticsrate-laworder-of-reaction