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Section A: Long Answer Questions

Attempt all / any as specified.

4 questions
1long14 marks

(a) Set up the differential equation of a damped harmonic oscillator and obtain its solution for the under-damped case. Hence define the logarithmic decrement and the quality factor (Q-factor) of the oscillator. (8)

(b) A body of mass 0.2 kg is attached to a spring of force constant 80 N/m and oscillates in a medium that exerts a damping force proportional to velocity with damping constant b = 4 kg/s. Calculate (i) the angular frequency of the damped oscillation and (ii) the time in which the amplitude falls to 1/e of its initial value. (6)

(a) Damped harmonic oscillator

A particle of mass mm experiences a restoring force kx-kx and a damping force bdxdt-b\dfrac{dx}{dt} proportional to velocity. Newton's second law gives

md2xdt2=kxbdxdtm\frac{d^2x}{dt^2} = -kx - b\frac{dx}{dt} d2xdt2+2βdxdt+ω02x=0\Rightarrow \frac{d^2x}{dt^2} + 2\beta\frac{dx}{dt} + \omega_0^2 x = 0

where 2β=bm2\beta = \dfrac{b}{m} (damping coefficient) and ω02=km\omega_0^2 = \dfrac{k}{m} (natural angular frequency).

Trying x=eαtx = e^{\alpha t} gives the auxiliary equation α2+2βα+ω02=0\alpha^2 + 2\beta\alpha + \omega_0^2 = 0, so

α=β±β2ω02\alpha = -\beta \pm \sqrt{\beta^2 - \omega_0^2}

Under-damped case (β<ω0\beta < \omega_0): the root is complex, α=β±iω\alpha = -\beta \pm i\omega' with ω=ω02β2\omega' = \sqrt{\omega_0^2 - \beta^2}. The solution is

x(t)=a0eβtcos(ωt+ϕ)\boxed{x(t) = a_0\, e^{-\beta t}\cos(\omega' t + \phi)}

This is an oscillation of angular frequency ω\omega' whose amplitude a0eβta_0 e^{-\beta t} decays exponentially with time.

Logarithmic decrement (λ\lambda): the natural logarithm of the ratio of successive amplitudes one period T=2π/ωT = 2\pi/\omega' apart:

λ=lnanan+1=βT=2πβω\lambda = \ln\frac{a_n}{a_{n+1}} = \beta T = \frac{2\pi\beta}{\omega'}

It measures how rapidly the amplitude dies away.

Quality factor (QQ): Q=2π×energy storedenergy lost per cycle=ω2βω02βQ = 2\pi \times \dfrac{\text{energy stored}}{\text{energy lost per cycle}} = \dfrac{\omega'}{2\beta} \approx \dfrac{\omega_0}{2\beta} for light damping. A high QQ means a sharply resonant, slowly decaying oscillator.

(b) Numerical

Given m=0.2m = 0.2 kg, k=80k = 80 N/m, b=4b = 4 kg/s.

ω02=km=800.2=400 s2,β=b2m=40.4=10 s1\omega_0^2 = \frac{k}{m} = \frac{80}{0.2} = 400\ \text{s}^{-2}, \qquad \beta = \frac{b}{2m} = \frac{4}{0.4} = 10\ \text{s}^{-1}

(i) Angular frequency of damped oscillation:

ω=ω02β2=400100=300=17.32 rad/s\omega' = \sqrt{\omega_0^2 - \beta^2} = \sqrt{400 - 100} = \sqrt{300} = 17.32\ \text{rad/s}

(ii) The amplitude factor is eβte^{-\beta t}. It falls to 1/e1/e when βt=1\beta t = 1:

t=1β=110=0.1 st = \frac{1}{\beta} = \frac{1}{10} = 0.1\ \text{s}

Results: ω17.3\omega' \approx 17.3 rad/s and t=0.1t = 0.1 s.

oscillationsdamped-oscillationsforced-oscillations
2long14 marks

(a) Explain the formation of Newton's rings by reflected light. Derive expressions for the diameters of the bright and dark rings and show that the diameter of the dark rings is proportional to the square root of the natural numbers. (9)

(b) In a Newton's rings experiment the diameter of the 10th dark ring changes from 1.40 cm to 1.27 cm when a liquid is introduced between the lens and the glass plate. Calculate the refractive index of the liquid. (5)

(a) Newton's rings by reflected light

When a plano-convex lens of large radius of curvature RR is placed on a flat glass plate, a thin wedge-shaped air film of variable thickness tt is formed between them. Monochromatic light incident normally is partly reflected from the top and bottom of the air film; these two beams interfere, producing concentric bright and dark circular fringes centred at the point of contact — Newton's rings.

For reflection at the lower (denser) surface there is an additional path change of λ/2\lambda/2 (phase change of π\pi). The effective path difference is

Δ=2μt+λ2(μ=1 for air)\Delta = 2\mu t + \frac{\lambda}{2} \quad (\mu = 1 \text{ for air})

Bright rings: 2t+λ2=nλ2t=(2n1)λ22t + \dfrac{\lambda}{2} = n\lambda \Rightarrow 2t = (2n-1)\dfrac{\lambda}{2}

Dark rings: 2t=nλ,n=0,1,2,2t = n\lambda,\quad n = 0,1,2,\dots

Geometry of the air film: if rr is the radius of a ring, r2=(2Rt)t2Rtr^2 = (2R - t)t \approx 2Rt (since tRt \ll R), so t=r22Rt = \dfrac{r^2}{2R}.

Diameter of dark rings (D=2rD = 2r): 2r22R=nλr2=nRλ2\cdot\dfrac{r^2}{2R} = n\lambda \Rightarrow r^2 = nR\lambda

Dn2=4nRλDn=2nRλ\boxed{D_n^2 = 4nR\lambda \Rightarrow D_n = 2\sqrt{nR\lambda}}

Thus DnnD_n \propto \sqrt{n} — the dark-ring diameter is proportional to the square root of the natural numbers 1,2,3,\sqrt{1},\sqrt{2},\sqrt{3},\dots

Diameter of bright rings: r2=(2n1)Rλ2Dn=2(2n1)Rλr^2 = \dfrac{(2n-1)R\lambda}{2} \Rightarrow D_n = \sqrt{2(2n-1)R\lambda}, i.e. Dn2n1D_n \propto \sqrt{2n-1}.

(b) Refractive index of the liquid

In air: Dn2=4nRλD_n^2 = 4nR\lambda. In a liquid of index μ\mu: Dn2=4nRλμD_n'^2 = \dfrac{4nR\lambda}{\mu}.

Dividing,

μ=Dn2Dn2=(1.40)2(1.27)2=1.9601.613=1.215\mu = \frac{D_n^2}{D_n'^2} = \frac{(1.40)^2}{(1.27)^2} = \frac{1.960}{1.613} = 1.215

Refractive index of the liquid μ1.22\mu \approx 1.22.

interferencenewtons-ringsthin-film
3long14 marks

(a) State Maxwell's equations in differential form for a non-conducting, charge-free medium and explain the physical significance of each equation, including the concept of displacement current. (8)

(b) Starting from Maxwell's equations, derive the wave equation for the electric field in free space and obtain an expression for the velocity of electromagnetic waves in vacuum. Show that this velocity equals the speed of light. (6)

(a) Maxwell's equations (charge-free, non-conducting medium)

For a region with ρ=0\rho = 0 and J=0\mathbf{J} = 0 (free space, permittivity ε0\varepsilon_0, permeability μ0\mu_0):

EquationDifferential formPhysical significance
Gauss (electric)E=0\nabla\cdot\mathbf{E} = 0No free charge; electric field lines are continuous (closed).
Gauss (magnetic)B=0\nabla\cdot\mathbf{B} = 0No magnetic monopoles; B\mathbf{B} lines form closed loops.
Faraday×E=Bt\nabla\times\mathbf{E} = -\dfrac{\partial \mathbf{B}}{\partial t}A time-varying magnetic field produces (induces) an electric field.
Ampère–Maxwell×B=μ0ε0Et\nabla\times\mathbf{B} = \mu_0\varepsilon_0\dfrac{\partial \mathbf{E}}{\partial t}A time-varying electric field produces a magnetic field.

Displacement current: Maxwell noticed Ampère's law ×B=μ0J\nabla\times\mathbf{B} = \mu_0\mathbf{J} fails for a charging capacitor (no conduction current between plates). He added a term ε0Et\varepsilon_0\dfrac{\partial \mathbf{E}}{\partial t}, the displacement current density Jd=ε0Et\mathbf{J}_d = \varepsilon_0\dfrac{\partial \mathbf{E}}{\partial t}. It is not a flow of charge but a changing electric flux that produces a magnetic field exactly like a real current, making the equations consistent and predicting EM waves.

(b) Wave equation and wave speed

Take the curl of Faraday's law:

×(×E)=t(×B)\nabla\times(\nabla\times\mathbf{E}) = -\frac{\partial}{\partial t}(\nabla\times\mathbf{B})

Using the identity ×(×E)=(E)2E\nabla\times(\nabla\times\mathbf{E}) = \nabla(\nabla\cdot\mathbf{E}) - \nabla^2\mathbf{E} and E=0\nabla\cdot\mathbf{E}=0:

2E=t(μ0ε0Et)-\nabla^2\mathbf{E} = -\frac{\partial}{\partial t}\left(\mu_0\varepsilon_0\frac{\partial \mathbf{E}}{\partial t}\right) 2E=μ0ε02Et2\boxed{\nabla^2\mathbf{E} = \mu_0\varepsilon_0\frac{\partial^2\mathbf{E}}{\partial t^2}}

Comparing with the standard wave equation 2E=1v22Et2\nabla^2\mathbf{E} = \dfrac{1}{v^2}\dfrac{\partial^2\mathbf{E}}{\partial t^2}, the wave speed is

v=1μ0ε0v = \frac{1}{\sqrt{\mu_0\varepsilon_0}}

Substituting μ0=4π×107\mu_0 = 4\pi\times10^{-7} H/m and ε0=8.854×1012\varepsilon_0 = 8.854\times10^{-12} F/m:

v=1(4π×107)(8.854×1012)=3×108 m/s=cv = \frac{1}{\sqrt{(4\pi\times10^{-7})(8.854\times10^{-12})}} = 3\times10^{8}\ \text{m/s} = c

This equals the measured speed of light, establishing that light is an electromagnetic wave.

electromagnetismmaxwells-equationsem-waves
4long14 marks

(a) Derive the time-independent Schrödinger wave equation for a particle of mass m moving in one dimension. (6)

(b) Apply it to a particle confined in a one-dimensional infinite potential well of width L. Obtain the normalized wave functions and the expression for the allowed energy levels, and sketch the wave functions and probability densities for the first three states. (8)

(a) Time-independent Schrödinger equation (1-D)

A particle of mass mm is described by a wavefunction. For a plane matter wave the time-dependent wavefunction is

Ψ(x,t)=ψ(x)eiEt/\Psi(x,t) = \psi(x)\,e^{-iEt/\hbar}

Start from the classical energy relation E=p22m+V(x)E = \dfrac{p^2}{2m} + V(x). Using the de Broglie relation and the operator correspondences EitE \to i\hbar\dfrac{\partial}{\partial t} and pixp \to -i\hbar\dfrac{\partial}{\partial x}, the time-dependent Schrödinger equation is

iΨt=22m2Ψx2+VΨi\hbar\frac{\partial\Psi}{\partial t} = -\frac{\hbar^2}{2m}\frac{\partial^2\Psi}{\partial x^2} + V\Psi

Substituting Ψ=ψ(x)eiEt/\Psi = \psi(x)e^{-iEt/\hbar}, the time part gives EψE\psi on the left, and dividing through by eiEt/e^{-iEt/\hbar}:

22md2ψdx2+V(x)ψ=Eψd2ψdx2+2m2(EV)ψ=0\boxed{-\frac{\hbar^2}{2m}\frac{d^2\psi}{dx^2} + V(x)\psi = E\psi \quad\Longleftrightarrow\quad \frac{d^2\psi}{dx^2} + \frac{2m}{\hbar^2}\big(E - V\big)\psi = 0}

This is the time-independent Schrödinger equation.

(b) Particle in a 1-D infinite potential well of width LL

Let V=0V = 0 for 0<x<L0 < x < L and V=V = \infty outside. Inside the well:

d2ψdx2+k2ψ=0,k2=2mE2\frac{d^2\psi}{dx^2} + k^2\psi = 0, \qquad k^2 = \frac{2mE}{\hbar^2}

General solution ψ=Asinkx+Bcoskx\psi = A\sin kx + B\cos kx.

Boundary conditions: ψ=0\psi = 0 at x=0x=0 and x=Lx=L (walls are impenetrable).

  • At x=0x=0: B=0ψ=AsinkxB = 0 \Rightarrow \psi = A\sin kx.
  • At x=Lx=L: AsinkL=0kL=nπ, n=1,2,3,A\sin kL = 0 \Rightarrow kL = n\pi,\ n = 1,2,3,\dots

So k=nπLk = \dfrac{n\pi}{L}.

Energy levels: from E=2k22mE = \dfrac{\hbar^2 k^2}{2m},

En=n2π222mL2=n2h28mL2,n=1,2,3,\boxed{E_n = \frac{n^2\pi^2\hbar^2}{2mL^2} = \frac{n^2 h^2}{8mL^2}, \quad n = 1,2,3,\dots}

The energy is quantized; the lowest (zero-point) energy is E1=h28mL20E_1 = \dfrac{h^2}{8mL^2} \neq 0.

Normalization: 0Lψ2dx=1A2 ⁣0Lsin2 ⁣nπxLdx=A2L2=1A=2L\displaystyle\int_0^L |\psi|^2\,dx = 1 \Rightarrow A^2\!\int_0^L\sin^2\!\frac{n\pi x}{L}\,dx = A^2\frac{L}{2} = 1 \Rightarrow A = \sqrt{\frac{2}{L}}.

ψn(x)=2LsinnπxL\boxed{\psi_n(x) = \sqrt{\frac{2}{L}}\sin\frac{n\pi x}{L}}

Sketches (described):

  • n=1n=1: ψ1\psi_1 is a single half-sine loop with a maximum at x=L/2x=L/2; ψ12|\psi_1|^2 has one hump peaked at the centre.
  • n=2n=2: ψ2\psi_2 has one full sine wave with a node at x=L/2x=L/2; ψ22|\psi_2|^2 shows two humps with zero probability at the centre and at the walls.
  • n=3n=3: ψ3\psi_3 has three half-loops (nodes at x=L/3,2L/3x=L/3, 2L/3); ψ32|\psi_3|^2 shows three humps.

In every case the wavefunction and probability density vanish at the walls, and the number of nodes increases with nn.

quantum-mechanicsschrodinger-equationparticle-in-a-box
B

Section B: Short Answer Questions

Attempt all / any as specified.

8 questions
5short7 marks

(a) Distinguish between Fresnel and Fraunhofer classes of diffraction. (3)

(b) A plane transmission grating has 5000 lines per cm. Find the angle of diffraction for the second-order principal maximum when light of wavelength 5890 Å is incident normally on the grating. (4)

(a) Fresnel vs Fraunhofer diffraction

FeatureFresnel diffractionFraunhofer diffraction
Source / screen distanceSource and/or screen at finite distance from apertureSource and screen effectively at infinity
WavefrontSpherical or cylindricalPlane
LensesNo lenses requiredConverging lenses used to make rays parallel and focus them
MathematicsMore complex; uses Fresnel zonesSimpler; treated with simple integration

(b) Grating: second-order maximum

Grating element (spacing) d=1N=15000 cm=2×106 m=2000d = \dfrac{1}{N} = \dfrac{1}{5000}\ \text{cm} = 2\times10^{-6}\ \text{m} = 2000 nm.

Grating equation: dsinθ=mλd\sin\theta = m\lambda with m=2m = 2, λ=5890 A˚=5.89×107\lambda = 5890\ \text{\AA} = 5.89\times10^{-7} m.

sinθ=mλd=2×5.89×1072×106=0.589\sin\theta = \frac{m\lambda}{d} = \frac{2\times5.89\times10^{-7}}{2\times10^{-6}} = 0.589 θ=sin1(0.589)=36.1\theta = \sin^{-1}(0.589) = 36.1^{\circ}

Angle of diffraction for the second order θ36.1\theta \approx 36.1^{\circ}.

diffractiondiffraction-grating
6short7 marks

(a) State and explain Brewster's law. Show that when light is incident at the polarizing angle, the reflected and refracted rays are mutually perpendicular. (4)

(b) Calculate the polarizing angle for light passing from air into glass of refractive index 1.54. (3)

(a) Brewster's law

When unpolarized light is incident on a transparent dielectric, the reflected light is completely plane-polarized at one particular angle of incidence called the polarizing (Brewster) angle θp\theta_p. Brewster's law states that the refractive index of the medium equals the tangent of the polarizing angle:

μ=tanθp\mu = \tan\theta_p

Reflected and refracted rays are perpendicular: By Snell's law μ=sinθpsinr\mu = \dfrac{\sin\theta_p}{\sin r}. By Brewster's law μ=sinθpcosθp\mu = \dfrac{\sin\theta_p}{\cos\theta_p}. Comparing,

sinr=cosθp=sin(90θp)r=90θp\sin r = \cos\theta_p = \sin(90^\circ - \theta_p) \Rightarrow r = 90^\circ - \theta_p

Therefore θp+r=90\theta_p + r = 90^\circ. Since the reflected ray makes angle θp\theta_p and the refracted ray makes angle rr with the normal on opposite sides, the angle between them is 180(θp+r)=90180^\circ - (\theta_p + r) = 90^\circ. Hence the reflected and refracted rays are mutually perpendicular at the polarizing angle.

(b) Polarizing angle for glass (μ=1.54\mu = 1.54)

θp=tan1(μ)=tan1(1.54)=57.0\theta_p = \tan^{-1}(\mu) = \tan^{-1}(1.54) = 57.0^{\circ}

Polarizing angle θp57\theta_p \approx 57^{\circ}.

polarizationbrewsters-lawdouble-refraction
7short7 marks

Explain the terms spontaneous emission, stimulated emission and population inversion. With the help of a suitable energy-level diagram, describe the principle of operation of a He-Ne laser.

Key terms

Spontaneous emission: An atom in an excited state E2E_2 spontaneously decays to a lower state E1E_1 emitting a photon of energy hν=E2E1h\nu = E_2 - E_1 at a random time and in a random direction. The emitted photons are incoherent.

Stimulated emission: An incident photon of energy hν=E2E1h\nu = E_2 - E_1 induces an excited atom to drop to E1E_1, emitting a second photon that is identical to the incident one — same frequency, phase, direction and polarization. This produces coherent amplification of light (the basis of laser action).

Population inversion: The non-equilibrium condition in which more atoms occupy the higher energy level than the lower one (N2>N1N_2 > N_1). It is essential for stimulated emission to dominate over absorption so that light is amplified. It is achieved by pumping (optical or electrical).

He–Ne laser

The active medium is a mixture of helium and neon (about 10:1) in a discharge tube; an electric discharge excites the He atoms.

Energy-level scheme (described):

  1. Electrons in the discharge excite He atoms to metastable levels F2F_2 (≈20.61 eV) and F3F_3 (≈19.81 eV).
  2. These He levels are nearly equal in energy to the Ne levels E6E_6 and E4E_4. By resonant collision the excited He atoms transfer their energy to Ne atoms (He returns to ground state), populating Ne levels E6E_6 and E4E_4. This creates population inversion between these Ne levels and the lower Ne levels.
  3. Stimulated transitions in neon give the laser output, the principal one being
E6E3:λ=6328 A˚(632.8 nm, red)E_6 \to E_3:\quad \lambda = 6328\ \text{\AA (632.8 nm, red)}

(other lines at 1.15 µm and 3.39 µm). 4. From E3E_3 the Ne atoms decay rapidly to E2E_2 and return to the ground state through collisions with the tube walls, keeping the lower laser level empty and sustaining the inversion.

A pair of mirrors (one fully reflecting, one partially reflecting) forms an optical resonator that builds up the coherent beam, which emerges as a continuous, highly monochromatic, coherent red beam.

laserslaser-actionpopulation-inversion
8short7 marks

(a) Define acceptance angle and numerical aperture of an optical fibre and derive an expression relating the numerical aperture to the refractive indices of the core and cladding. (4)

(b) An optical fibre has a core of refractive index 1.50 and a cladding of refractive index 1.47. Calculate its numerical aperture and acceptance angle. (3)

(a) Acceptance angle and numerical aperture

Acceptance angle (θa\theta_a): the maximum angle (measured from the fibre axis) at which light entering the core end face is guided down the fibre by total internal reflection. Rays entering within this angle propagate; rays outside it escape into the cladding.

Numerical aperture (NA): the light-gathering ability of the fibre, defined as NA=sinθa\text{NA} = \sin\theta_a (in air).

Derivation: Let the core index be n1n_1, cladding index n2n_2 (n1>n2n_1 > n_2) and surrounding medium n0n_0. For a ray to be guided, it must strike the core–cladding boundary at the critical angle θc\theta_c, where sinθc=n2/n1\sin\theta_c = n_2/n_1.

For the limiting ray entering at θa\theta_a, Snell's law at the end face gives n0sinθa=n1sinθrn_0\sin\theta_a = n_1\sin\theta_r, where θr=90θc\theta_r = 90^\circ - \theta_c. Thus sinθr=cosθc=1sin2θc=1n22/n12\sin\theta_r = \cos\theta_c = \sqrt{1 - \sin^2\theta_c} = \sqrt{1 - n_2^2/n_1^2}.

n0sinθa=n11n22n12=n12n22n_0\sin\theta_a = n_1\sqrt{1 - \frac{n_2^2}{n_1^2}} = \sqrt{n_1^2 - n_2^2}

Taking n0=1n_0 = 1 (air):

NA=sinθa=n12n22\boxed{\text{NA} = \sin\theta_a = \sqrt{n_1^2 - n_2^2}}

(b) Numerical

n1=1.50, n2=1.47n_1 = 1.50,\ n_2 = 1.47.

NA=1.5021.472=2.252.1609=0.0891=0.29850.30\text{NA} = \sqrt{1.50^2 - 1.47^2} = \sqrt{2.25 - 2.1609} = \sqrt{0.0891} = 0.2985 \approx 0.30 θa=sin1(0.2985)=17.4\theta_a = \sin^{-1}(0.2985) = 17.4^{\circ}

NA 0.30\approx 0.30, acceptance angle θa17.4\theta_a \approx 17.4^{\circ}.

fibre-opticstotal-internal-reflectionnumerical-aperture
9short7 marks

(a) Explain the Hall effect and derive an expression for the Hall coefficient. State two applications of the Hall effect. (4)

(b) The Hall coefficient of a specimen of doped silicon is found to be 3.66 × 10⁻⁴ m³/C. Determine the type and concentration of the charge carriers. (3)

(a) Hall effect and Hall coefficient

When a current-carrying conductor or semiconductor is placed in a magnetic field perpendicular to the current, a transverse voltage (the Hall voltage VHV_H) appears across the specimen, perpendicular to both the current and the field. This is the Hall effect.

Let current density JxJ_x flow along xx and field BzB_z along zz. Moving charges experience the magnetic (Lorentz) force qvxBzqv_x B_z, which deflects them sideways and builds up a transverse electric field EyE_y until it balances the magnetic force:

qEy=qvxBzEy=vxBzqE_y = qv_x B_z \Rightarrow E_y = v_x B_z

With Jx=nqvxJ_x = nqv_x (carrier density nn, charge qq), vx=Jx/(nq)v_x = J_x/(nq), so

Ey=JxBznqE_y = \frac{J_x B_z}{nq}

The Hall coefficient is defined as

RH=EyJxBz=1nq\boxed{R_H = \frac{E_y}{J_x B_z} = \frac{1}{nq}}

Its sign gives the sign of the charge carriers: RH>0R_H > 0 for p-type (holes), RH<0R_H < 0 for n-type (electrons).

Applications: (i) determination of the type, sign and concentration of charge carriers; (ii) measurement of magnetic field (Hall probe / gaussmeter); also measurement of carrier mobility.

(b) Numerical

RH=+3.66×104 m3/CR_H = +3.66\times10^{-4}\ \text{m}^3/\text{C}. The positive sign indicates p-type material (holes are the majority carriers).

RH=1nqn=1RHq=1(3.66×104)(1.6×1019)R_H = \frac{1}{nq} \Rightarrow n = \frac{1}{R_H\,q} = \frac{1}{(3.66\times10^{-4})(1.6\times10^{-19})} n=15.856×1023=1.71×1022 m3n = \frac{1}{5.856\times10^{-23}} = 1.71\times10^{22}\ \text{m}^{-3}

Carriers are holes (p-type), concentration n1.71×1022 m3n \approx 1.71\times10^{22}\ \text{m}^{-3}.

semiconductor-physicshall-effect
10short7 marks

(a) Distinguish between polar and non-polar dielectrics. Explain the different types of polarization that can occur in a dielectric material. (4)

(b) State the Clausius-Mossotti relation and explain the physical quantities involved in it. (3)

(a) Polar vs non-polar dielectrics; types of polarization

Non-polar dielectrics: molecules in which the centres of positive and negative charge coincide, so they have no permanent dipole moment in the absence of a field (e.g. H2H_2, N2N_2, O2O_2, CO2CO_2). A dipole is induced only when a field is applied.

Polar dielectrics: molecules with an asymmetric structure so the charge centres do not coincide, giving a permanent dipole moment even without a field (e.g. H2OH_2O, HClHCl, NH3NH_3). Without a field the dipoles are randomly oriented; a field tends to align them.

Types of polarization:

  1. Electronic polarization – displacement of the electron cloud relative to the nucleus by the field; present in all dielectrics, very fast.
  2. Ionic (atomic) polarization – relative displacement of positive and negative ions in ionic solids.
  3. Orientational (dipolar) polarization – partial alignment of permanent dipoles in polar dielectrics; temperature dependent.
  4. Space-charge (interfacial) polarization – accumulation of charges at interfaces/grain boundaries in inhomogeneous materials.

(b) Clausius–Mossotti relation

εr1εr+2=Nα3ε0\frac{\varepsilon_r - 1}{\varepsilon_r + 2} = \frac{N\alpha}{3\varepsilon_0}

where

  • εr\varepsilon_r = relative permittivity (dielectric constant) of the material,
  • NN = number of molecules (polarizable units) per unit volume,
  • α\alpha = molecular polarizability (dipole moment induced per unit local field),
  • ε0\varepsilon_0 = permittivity of free space.

It relates the macroscopic dielectric constant εr\varepsilon_r to the microscopic polarizability α\alpha, accounting for the local (internal) field acting on each molecule, and is valid for non-polar dielectrics.

dielectricspolarizationclausius-mossotti
11short7 marks

(a) Distinguish between diamagnetic, paramagnetic and ferromagnetic materials with one example of each. (3)

(b) Draw and explain the B-H hysteresis loop of a ferromagnetic material. Indicate retentivity and coercivity on the loop and state the significance of the area enclosed by the loop. (4)

(a) Diamagnetic, paramagnetic and ferromagnetic materials

PropertyDiamagneticParamagneticFerromagnetic
Net atomic momentZero (no permanent dipole)Permanent but randomly orientedPermanent, strongly coupled (domains)
Behaviour in fieldWeakly repelled; magnetized opposite to fieldWeakly attracted; aligns with fieldStrongly attracted; large magnetization
Relative permeability μr\mu_rSlightly <1<1Slightly >1>11\gg 1
Susceptibility χ\chiSmall, negativeSmall, positiveLarge, positive
ExampleBismuth (Cu, water)Aluminium (Pt, O2O_2)Iron (Co, Ni)

(b) B–H hysteresis loop

When a ferromagnetic specimen is taken through a complete cycle of magnetization, the plot of flux density BB against magnetizing field HH does not retrace itself but forms a closed loop — hysteresis (B lags behind H).

Description of the loop (described in words):

  • Starting unmagnetized, increasing HH raises BB along the initial curve OaO\to a up to saturation.
  • Reducing HH to zero leaves a residual flux density ObOb = retentivity (remanence) BrB_r — the material stays magnetized.
  • Reversing HH to a value OcOc reduces BB to zero; this reverse field is the coercivity HcH_c — the field needed to fully demagnetize the specimen.
  • Continuing the cycle traces the full symmetric loop a ⁣ ⁣b ⁣ ⁣c ⁣ ⁣d ⁣ ⁣e ⁣ ⁣f ⁣ ⁣aa\!-\!b\!-\!c\!-\!d\!-\!e\!-\!f\!-\!a.

Significance of the loop area: the area enclosed by the B–H loop equals the energy dissipated as heat (hysteresis loss) per unit volume per cycle of magnetization. Therefore:

  • Soft magnetic materials (e.g. soft iron) have a thin loop (small area, low loss, low HcH_c) → suitable for transformer cores and electromagnets.
  • Hard magnetic materials (e.g. steel) have a wide loop (large area, high retentivity and coercivity) → suitable for permanent magnets.
magnetismmagnetic-materialshysteresis
12short7 marks

(a) State Heisenberg's uncertainty principle and use it to explain why an electron cannot exist inside the nucleus. (4)

(b) Calculate the de Broglie wavelength of an electron that has been accelerated through a potential difference of 100 V. (3)

(a) Heisenberg's uncertainty principle

It is impossible to determine simultaneously and with unlimited precision both the position and the momentum of a particle. The product of the uncertainties satisfies

ΔxΔp2(=h2π)\Delta x\,\Delta p \gtrsim \frac{\hbar}{2}\quad\left(\hbar = \frac{h}{2\pi}\right)

Electron cannot exist inside the nucleus: A nucleus has radius 1014\sim 10^{-14} m, so if an electron were confined inside it, Δx1014\Delta x \le 10^{-14} m. Then

Δp2Δx=1.055×10342×10145.3×1021 kg\cdotpm/s\Delta p \ge \frac{\hbar}{2\Delta x} = \frac{1.055\times10^{-34}}{2\times10^{-14}} \approx 5.3\times10^{-21}\ \text{kg·m/s}

The minimum momentum pΔpp \approx \Delta p, giving a (relativistic) energy Epc(5.3×1021)(3×108)1.6×1012E \approx pc \approx (5.3\times10^{-21})(3\times10^8) \approx 1.6\times10^{-12} J 10\approx 10 MeV.

An electron bound in the nucleus would thus need an energy of the order of tens of MeV. But electrons emitted in β\beta-decay have energies of only a few MeV, and no nuclear binding can supply ~tens of MeV to hold an electron. Hence an electron cannot exist inside the nucleus.

(b) de Broglie wavelength of an electron accelerated through 100 V

The kinetic energy gained is eVeV, and the wavelength is

λ=h2meV=12.27V A˚(V in volts)\lambda = \frac{h}{\sqrt{2meV}} = \frac{12.27}{\sqrt{V}}\ \text{\AA} \quad(V \text{ in volts})

Substituting V=100V = 100 V:

λ=12.27100=12.2710=1.227 A˚=1.227×1010 m\lambda = \frac{12.27}{\sqrt{100}} = \frac{12.27}{10} = 1.227\ \text{\AA} = 1.227\times10^{-10}\ \text{m}

de Broglie wavelength λ1.23 A˚=0.123\lambda \approx 1.23\ \text{\AA} = 0.123 nm.

quantum-mechanicsuncertainty-principlematter-waves

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